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Which of the following factors primarily causes the ionization enthalpy to increase across a period in the modern periodic table?
Free Technical Assistant( Kerala Drugs Control ) Practice Questions
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Q1. Which of the following factors primarily causes the ionization enthalpy to increase across a period in the modern periodic table?
- Increase in atomic radius
- Increase in effective nuclear charge
- Increase in electron shielding
- Decrease in nuclear charge
Q2. Which factor primarily causes the decrease in ionization enthalpy down a group in the periodic table?
- Increase in nuclear charge
- Increase in atomic radius and shielding effect
- Decrease in number of electrons
- Increase in effective nuclear charge
Q3. Consider two elements, X and Y, in the same group of the periodic table where Y is below X. Which statement correctly compares their atomic radii?
- Element X has a larger atomic radius than element Y.
- Element Y has a larger atomic radius than element X.
- Both elements have the same atomic radius.
- Atomic radius depends only on the number of protons, so cannot be compared.
Q4. Consider the elements magnesium (Mg) and aluminum (Al). Which one has a higher first ionization enthalpy and why?
- Mg has higher ionization enthalpy due to completely filled s-orbital
- Al has higher ionization enthalpy because it has more protons
- Both have the same ionization enthalpy as they are in the same period
- Al has lower ionization enthalpy due to electron entering a p-orbital
Q5. Which of the following best explains the trend in ionic radii of isoelectronic ions as the atomic number increases?
- Ionic radius increases due to more electron-electron repulsion
- Ionic radius decreases due to increasing nuclear charge pulling electrons closer
- Ionic radius remains constant because the number of electrons is the same
- Ionic radius fluctuates randomly with atomic number
Q6. Which of the following statements best defines the Modern Periodic Law?
- Properties of elements are a periodic function of their atomic masses.
- Properties of elements are a periodic function of their atomic numbers.
- Elements are arranged in order of increasing density.
- Elements are grouped based on their physical states at room temperature.
Q7. Which of the following trends correctly describes the variation of first ionization enthalpy across a period in the modern periodic table?
- It decreases from left to right across a period
- It remains constant across a period
- It generally increases from left to right across a period
- It fluctuates randomly with no trend
Q8. Which of the following best explains why ionization enthalpy decreases down a group despite increasing nuclear charge?
- Increase in atomic radius and electron shielding
- Decrease in number of electron shells
- Increase in effective nuclear charge
- Decrease in nuclear charge
Q9. Consider the ions Na+, Mg2+, and Al3+. Which of the following correctly ranks their ionic radii from largest to smallest?
- Na+ > Mg2+ > Al3+
- Al3+ > Mg2+ > Na+
- Mg2+ > Na+ > Al3+
- Na+ > Al3+ > Mg2+
Q10. Which of the following best explains the general trend in atomic radii across a period in the modern periodic table?
- Atomic radius increases due to increasing number of protons.
- Atomic radius decreases due to increasing effective nuclear charge.
- Atomic radius remains constant because electron shielding is unchanged.
- Atomic radius increases due to addition of electron shells.
Q11. Calculate the approximate atomic radius of an element if the effective nuclear charge (Z_eff) experienced by its outermost electron is 5 and the principal quantum number (n) is 3, using the simplified formula: Atomic radius ā n² / Z_eff. Which of the following values is closest?
- 1.8 (arbitrary units)
- 2.4 (arbitrary units)
- 3.6 (arbitrary units)
- 5.0 (arbitrary units)
Q12. Calculate the effective nuclear charge (Zeff) experienced by the outermost electrons of Mg2+ ion, given that Mg has atomic number 12 and the shielding constant (S) for the 10 electrons is approximately 10. Use Zeff = Z - S.
- 2
- 10
- 12
- 22
Q13. Consider two elements X and Y where X has atomic number 15 and Y has atomic number 16. According to the Modern Periodic Law, which of the following is true about their chemical properties?
- They have completely different chemical properties because their atomic masses differ.
- They have similar chemical properties because they are in the same group.
- They have different chemical properties because they belong to different groups.
- Their chemical properties depend only on their physical states.
Q14. Given the ionic radii of O2- (140 pm), F- (133 pm), and Na+ (102 pm), which of the following statements is true regarding their sizes?
- O2- is smaller than F- due to higher nuclear charge
- Na+ is the smallest because it has the highest positive charge
- F- is larger than O2- because it has fewer electrons
- All ions have the same size because they are isoelectronic
Q15. What is the correct definition of ionization enthalpy?
- Energy released when an electron is added to a neutral atom
- Energy required to remove one mole of electrons from one mole of gaseous atoms
- Energy required to break one mole of bonds in a molecule
- Energy released when one mole of gaseous atoms gains an electron